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Bioproducts

Winter 2016

Standing up for lignins

There’s a lot of carbon in a tree. And it’s carbon already circulating through the biosphere, so moving it from tree to degradable product, and then back into the soil as it decomposes results in a zero sum carbon game. Compare that with petroleum, where “nodding donkeys” are constantly bringing anciently sequestered carbon back into circulation, and trees win, hands down.

Except for one hitch. A lot of that carbon is bound up in lignins. Chemists speak sternly of lignin, as if talking about a willful child. Lignin, they say, is a recalcitrant molecule. It’s really tough—and takes a lot of external activation energy—to liberate … » More …